Heksogen

Heksogen
	1,3,5-Trinitroperhidro-1,3,5-triazin
Drugi nazivi	RDX; ciklonit; 1,3,5-Trinitro-1,3,5-triazacikloheksan; 1,3,5-Trinitroheksahidro-s-triazin; Ciklotrimetilenetrinitramin
Identifikacija
CAS registarski broj	121-82-4
PubChem	8490
ChemSpider	8177
UN broj	0072, 0391, 0483
ChEBI	24556
Jmol-3D slike	Slika 1
SMILES
	C1N(CN(CN1[N+](=O)[O-])[N+](=O)[O-])[N+](=O)[O-]
InChI
	InChI=1S/C3H6N6O6/c10-7(11)4-1-5(8(12)13)3-6(2-4)9(14)15/h1-3H2 ; Kod: XTFIVUDBNACUBN-UHFFFAOYSA-N InChI=1/C3H6N6O6/c10-7(11)4-1-5(8(12)13)3-6(2-4)9(14)15/h1-3H2; Kod: XTFIVUDBNACUBN-UHFFFAOYAY
Svojstva
Molekulska formula	C3H6N6O6
Molarna masa	222.12 g mol−1
Agregatno stanje	Bezbojni kristali
Gustina	1,82 g/cm3
Tačka topljenja	205.5 °C, 479 K, 402 °F
Tačka ključanja	234 °C, 507 K, 453 °F
Podaci o eksplozivu
Osetljivost na šok	Nizak
Osetljivost na trenje	Nizak
Eksplozivna brzina	8750 m/s
RE faktor	1,60
Opasnost
Opasnost u toku rada	Eksploziv
	(šta je ovo?) (verifikuj) ; Ukoliko nije drugačije napomenuto, podaci se odnose na standardno stanje (25 °C, 100 kPa) materijala
	Infobox references

Heksogen (RDX) je eksplozivni nitroamin sa širokim spektrom vojnih i industrijskih upotreba. On je razvijen kao eksploziv koji je moćniji od TNT-a i u znatnoj meri je korišten tokom Drugog svetskog rata. Heksogen je takođe poznat kao ciklonit (posebno na nemačkom govornom području), i T4. Njegovo hemijsko ime je ciklotrimetilentrinitramin (ciklotrimetilen-trinitramin, ciklotrimetilen trinitramin).

U svom čistom stanju RDX je bela kristalna materija. On se često koristi u smeši sa drugim eksplozivima i plastifikatorima. RDX je stabilan tokom skladištenja i smatra se jednim od najmoćnijih i najrazornijih eksploziva.^[4]

Reference uredi

↑ Li Q, Cheng T, Wang Y, Bryant SH (2010). „PubChem as a public resource for drug discovery.”. Drug Discov Today 15 (23-24): 1052-7. DOI:10.1016/j.drudis.2010.10.003. PMID 20970519. edit
↑ Evan E. Bolton, Yanli Wang, Paul A. Thiessen, Stephen H. Bryant (2008). „Chapter 12 PubChem: Integrated Platform of Small Molecules and Biological Activities”. Annual Reports in Computational Chemistry 4: 217-241. DOI:10.1016/S1574-1400(08)00012-1.
↑ Hettne KM, Williams AJ, van Mulligen EM, Kleinjans J, Tkachenko V, Kors JA. (2010). „Automatic vs. manual curation of a multi-source chemical dictionary: the impact on text mining”. J Cheminform 2 (1): 3. DOI:10.1186/1758-2946-2-3. PMID 20331846. edit
↑ Department of the Army Technical Manual TM 9-1300-214: Military Explosives. Headquarters, Department of the Army (United States).

Literatura uredi

Akhavan, Jacqueline (2004), The Chemistry of Explosives, Cambridge, UK: Royal Society of Chemistry, ISBN 0-85404-640-2
Agrawal, Jai Prakhash.; Hodgson, Robert Dale (2007), Organic Chemistry of Explosives, Wiley, ISBN 978-0-470-02967-1
Bachmann, W. E.; Sheehan, John C. (May 1949), „A New Method of Preparing the High Explosive RDX”, Journal of the American Chemical Society 71 (5): 1842-1845, DOI:10.1021/ja01173a092
US 2680671, Šablon:Cite patent/authors, "Method of Treating Cyclonite Mixtures", published 16. 7. 1943., issued 8. 6. 1954.
US 2798870, Šablon:Cite patent/authors, "Method for Preparing Explosives", published 16. 7. 1943., issued 9. 7. 1957.
Baxter III, James Phinney (1968) [1946], Scientists Against Time (MIT Paperback izd.), Cambridge, MA: MIT Press, ISBN 978-0-262-52012-6, OCLC 476611116
Cocroft, Wayne D. (2000). Dangerous Energy: The archaeology of gunpowder and military explosives manufacture. Swindon: English Heritage. ISBN 1-85074-718-0.
Cooper, Paul W. (1996), Explosives Engineering, New York: Wiley-VCH, ISBN 0-471-18636-8
Davis, Tenney L. (1943), The Chemistry of Powder and Explosives, II, New York: John Wiley & Sons Inc.
Elderfield, Robert C. (1960), Werner Emanual Bachmann: 1901-1951, Washington DC: National Academy of Sciences
Gartz, Jochen (2007) (German), Vom griechischen Feuer zum Dynamit: eine Kulturgeschichte der Explosivstoffe‎ (From Greek fire to dynamite: A cultural history of explosives), Hamburg: E. S. Mittler & Sohn, ISBN 978-3-8132-0867-2
Gilman, Henry (1953), „The Chemistry of Explosives”, Organic Chemistry an Advanced Treatise, III, Wiley; Chapman & Hall, pp. 985-986
Hale, George C. (November 3, 1925), „The Nitration of Hexamethylenetetramine”, Journal of the American Chemical Society 47 (11): 2754-2763, DOI:10.1021/ja01688a017
Hampton, L. D. (15. 6. 1960.), The Development of RDX Composition CH-6, White Oak, MD: U. S. Naval Ordnance Laboratory, NavOrd Report 680, arhivirano iz originala na datum 2012-10-06, pristupljeno 2014-04-11
DE 104280, Šablon:Cite patent/authors, issued 14. 6. 1899. .
GB 145791, Šablon:Cite patent/authors, "Improvements relating to Explosives", issued 17. 3. 1921.
US 1402693, Šablon:Cite patent/authors, "Explosive", issued 3. 1. 1922.
Hornby, William (1958), Factories and Plant, History of the Second World War: United Kingdom Civil Series, London: Her Majesty's Stationery Office; Longmans, Green and Co.
MacDonald and Mack Partnership (August 1984), Final Properties Report: Newport Army Ammunition Plant, National Park Service, AD-A175 818, arhivirano iz originala na datum 2011-04-29, pristupljeno 2014-04-11
Meyer, Rudolf (1987), Explosives (3rd izd.), VCH Publishers, ISBN 0-89573-600-4
GB 595354, Šablon:Cite patent/authors, "Method of Preparing 1.3.5. Trinitro Hexahydro S-Triazine", issued 3. 12. 1947.
Simmons, W.H.; Forster, A.; Bowden, R. C. (August 1948), „The Manufacture of R.D.X. in Great Britain: Part II – Raw Materials and Ancillary Processes”, The Industrial Chemist 24: 530-545
Simmons, W.H.; Forster, A.; Bowden, R. C. (September 1948), „The Manufacture of R.D.X. in Great Britain: Part III – Production of the Explosive”, The Industrial Chemist 24: 593-601
Urbański, Tadeusz (1967), Chemistry and Technology of Explosives, III (First English izd.), Warszawa: PWN - Polish Scientific Publishers and Pergamon Press, OCLC 499857211 . Translation by Marian Jurecki, edited by Sylvia Laverton. See also ISBN 978-0-08-010401-0.
Urbański translation http://openlibrary.org/books/OL3160546M/Chemistry_and_technology_of_explosives, Macmillan, NY, 1964, ISBN 0-08-026206-6.
Department of the Army Technical Manual TM 9-1300-214: Military Explosives. Headquarters, Department of the Army (United States).

Spoljašnje veze uredi

Portal Hemija

NLM Hazardous Substances Databank (US) – Cyclonite (RDX)
GlobalSecurity.org, Explosives - Compositions, Alexandria, VA: GlobalSecurity.org, pristupljeno 1. 9. 2010

[1] Li Q, Cheng T, Wang Y, Bryant SH (2010). „PubChem as a public resource for drug discovery.”. Drug Discov Today 15 (23-24): 1052-7. DOI:10.1016/j.drudis.2010.10.003. PMID 20970519. edit

[2] Evan E. Bolton, Yanli Wang, Paul A. Thiessen, Stephen H. Bryant (2008). „Chapter 12 PubChem: Integrated Platform of Small Molecules and Biological Activities”. Annual Reports in Computational Chemistry 4: 217-241. DOI:10.1016/S1574-1400(08)00012-1.

[3] Hettne KM, Williams AJ, van Mulligen EM, Kleinjans J, Tkachenko V, Kors JA. (2010). „Automatic vs. manual curation of a multi-source chemical dictionary: the impact on text mining”. J Cheminform 2 (1): 3. DOI:10.1186/1758-2946-2-3. PMID 20331846. edit

[Army_TM-4] Department of the Army Technical Manual TM 9-1300-214: Military Explosives. Headquarters, Department of the Army (United States).

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